Chemoselective Nitrosylation of Anilines and Alkynes via Fragmentary or Complete NO Incorporation
نویسندگان
چکیده
منابع مشابه
Rapid chemoselective bioconjugation through oxidative coupling of anilines and aminophenols.
A highly efficient protein bioconjugation method is described involving addition of anilines to o-aminophenols in the presence of sodium periodate. The reaction takes place in aqueous buffer at pH 6.5 and can reach high conversion in 2-5 min. The major product was characterized using X-ray crystallography, which revealed that an unprecedented oxidative ring contraction occurs after the coupling...
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Development of multicatalytic approach consisting of two or more mechanistically distinct catalytic steps using a single-site catalyst for rapid and straightforward access of structurally complex molecules under eco-benign conditions has significance in contemporary science. We have developed herein a rhodium-catalysed C-H activation strategy which uses an unprotected anilines and an electron-d...
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ژورنال
عنوان ژورنال: Chem
سال: 2018
ISSN: 2451-9294
DOI: 10.1016/j.chempr.2018.03.008